A Simple Organometallic Fluoride Sensor
Analytical / Inorganic

A Simple Organometallic Fluoride Sensor

Title:  Stibonium Ions for the Fluorescence Turn-On Sensing of F– in Drinking Water at Parts per Million Concentrations DOI: 10.1021/ja308194w Author:  Iou-Sheng Ke a, Mykhaylo Myahkostupov b, Felix N. Castellano *b, and François P. Gabbaï *a Journal:  Journal of American Chemical Society Affiliation:  a) Department of Chemistry, Texas A&M University, College Station, Texas, USA; b) Department of Chemistry and Center for … Continue reading

Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond
General Interest / Inorganic

Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond

Title:  Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond DOI:  10.1126/science.1221138 Author:  Holger Braunschweig, Rian D. Dewhurst, Kai Hammond, Jan Mies, Krzysztof Radacki, Alfredo Vargas Journal:  Science Affiliation:  Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany Take-home Importance According to the Authors:  Homoatomic triple bonds between main-group elements have been restricted to alkynes, … Continue reading

Electrocatalytically Active Graphene–Porphyrin MOF Composite for Oxygen Reduction Reaction
Inorganic / Materials / Nanotechnology

Electrocatalytically Active Graphene–Porphyrin MOF Composite for Oxygen Reduction Reaction

Title:  Electrocatalytically Active Graphene–Porphyrin MOF Composite for Oxygen Reduction Reaction DOI:  10.1021/ja211433h Author:  Maryam Jahan, Qiaoliang Bao, and Kian Ping Loh Journal:  Journal of the American Chemical Society Affiliation:  Graphene Research Centre, Department of Chemistry, National University of Singapore, Singapore Take-home Importance According to the Authors: By reacting the pyridine-functionalized graphene with iron–porphyrin, a graphene–metalloporphyrin MOF with enhanced catalytic activity for … Continue reading

CO2 Reduction on Tin Electrodes and Enhanced Activity for Tin/Tin Oxide Thin-Film Catalysts
Inorganic / Materials

CO2 Reduction on Tin Electrodes and Enhanced Activity for Tin/Tin Oxide Thin-Film Catalysts

Title:  Tin Oxide Dependence of the CO2 Reduction Efficiency on Tin Electrodes and Enhanced Catalytic Activity for Tin/Tin-Oxide Thin Film Catalyst DOI:  10.1021/ja2108799 Author:  Yihong Chen and Matthew W. Kanan Journal:  Journal of the American Chemical Society Affiliation:  Department of Chemistry, Stanford University, Stanford, California, United States Take-home Importance According to the Authors: In aqueous … Continue reading

Solid-State Solvatochromism
Inorganic / Materials

Solid-State Solvatochromism

Title: Ionic Crystals of {[Ni(phen)3]2Ge4S10}-xSol, Showing Solid-State Solvatochromism and Rapid Solvent-Induced Recrystallization Authors: Wen-Qin Mu, Qin-Yu Zhu, Li-Sheng You, Xu Zhang, Wen Luo, Guo-Qing Bian, Jie Dia Journal: Inorganic Chemistry Take Home Importance According to Blogger: A solid material which could rapidly change color depending on what solvent was introduced is reported, with potential sensing applications. Summary: Materials which rapidly … Continue reading