Thanksgiving chemistry- cranberries and your blood

To do the biological study of how particular (good) chemicals like antioxidants affect people, there needs to be a quick, reliable, and consistent way to measure those chemicals in humans. Furthermore, a good method would test for multiple chemicals, because the health benefits from some chemicals only exist in the presence of others (phenolic acids and flavonoids in this case). The authors of this paper demonstrate a gas-chromatography mass-spectrometry (GC-MS) method to investigate how some of the chemicals present in cranberries (from cranberry juice) go into your bloodstream after you ingest them.

Shrinky-Dink Science

Title: Self-folding of polymer sheets using local light absorption Authors: Ying Liu, Julie K. Boyles, Jan Genzer and Michael D. Dickey Journal: Soft Matter Affiliation: Department of Chemical and Biomolecular Engineering, North Carolina State University As a kid you may have played with Shrinky-Dinks.  I remember…

Continuous in situ generation and reaction of phosgene in a microflow system

Title:  Continuous in situ generation and reaction of phosgene in a microflow system Authors:  Shinichiro Fuse, Nobutake Tanabe, and Takashi Takahashi* Journal:  Chemical Communications Affiliation:  Department of Applied Chemistry, Tokyo Institute of Technology, Tokyo, Japan. Take-Home Importance according to the Authors:  Continuous in situ generation of…

Stand with Science

MIT news has a very interesting article this week about a student group at MIT,  the Science Policy Initiative, that has started a petition to Congress asking to avoid cutting federal funding for R&D.  I encourage everyone to take a look at the petition.  I personally believe that…

Stack Exchange Strategies for the Synthesis of Covalent Double-Channel Photosystems by Self-Organizing Surface-Initiated Polymerization

Title: Stack Exchange Strategies for the Synthesis of Covalent Double-Channel Photosystems by Self-Organizing Surface-Initiated Polymerization Authors:  N. Sakai and S. Matile Journal: Journal of the American Chemical Society Affiliation: University of Geneva, Geneva, Switzerland Take Home Importance: Well-ordered polymeric ‘columns’ of different chromophores in the same polymer were prepared…

Molecular-scale versions of diodes invert “normal” diode behavior

Article Title: Inverse Rectification in Donor-Acceptor Molecular Heterojunctions Authors:  Shannon K. Yee, Jibin Sun, Pierre Darancet, T. Don Tilley, Arun Majumdar, Jeffrey B. Neaton,  and Rachel A. Segalman Journal: ACS Nano Affiliation: University of California- Berkeley: Department of Mechanical Engineering, Department of Chemical and Biomolecular Engineering, Department of…

Sensing Potassium

Title of Post: Sensing Potassium Title:  A New Highly Selective Fluorescent K+ Sensor Authors: Xianfeng Zhou, Fengyu Su, Yanqing Tian, Cody Youngbull, Roger H. Johnson, and Deirdre R. Meldrum Journal: Journal of the American Chemical Society Affiliation: Center for Biosignatures Discovery Automation, Biodesign Institute, Arizona State…

Chemistry Blog Carnival!

I’m sorry it took me so long to get a post out on this, but the good people at the IYC Blog (part of the C&EN family) put together a wonderful post about all of the Chemistry Blog Carnival submissions – http://cenblog.org/iyc-2011/2011/10/favorite_reactions_chemistry_blogging_carnival/ As you may remember I…

Tiny stamps make patterns with different energy levels for LEDs

Title: Spatially Modulating Interfacial Properties of Transparent Conductive Oxides: Patterning Work Function with Phosphonic Acid Self-Assembled Monolayers Authors: Kristina M. Knesting , Peter J. Hotchkiss , Bradley A. MacLeod , Seth R. Marder , and David S. Ginger Journal: Advanced Materials Affiliation: Department of Chemistry, University of Washington, and School of Chemistry and…

Using Computers for Rational Asymmetric Catalyst Design

Title: Three-Dimensional Correlation of Steric and Electronic Free Energy Relationships Guides Asymmetric Propargylation Author:  Kaid C. Harper, Matthew S. Sigman* Journal:  Science Affiliation:  Department of Chemistry, University of Utah, 315 South 1400 East Rm. 2020 Salt Lake City, Utah 84112-0850       In chemistry today, there is often…

Electrochemical Mechanism of Ion–Ionophore Recognition at Plasticized Polymer Membrane/Water Interfaces

Title:  Electrochemical Mechanism of Ion–Ionophore Recognition at Plasticized Polymer Membrane/Water Interfaces Author:  Ryoichi Ishimatsu, Anahita Izadyar, Benjamin Kabagambe, Yushin Kim, Jiyeon Kim, and Shigeru Amemiya Journal:  Journal of the American Chemical Society Affiliation:  Department of Chemistry, University of Pittsburgh, 219 Parkman Avenue, Pittsburgh, Pennsylvania, 15260 Take…

Chemistry on Mars: Making Perchlorates

Title: Photooxidation of Chloride by Oxide Minerals: Implications for Perchlorate on Mars Authors: Jennifer D. Schuttlefield†, Justin B. Sambur†, Melissa Gelwicks†, Carrick M. Eggleston‡, and B. A. Parkinson*†§ Journal: Journal of the American Chemical Society Affiliation: †Department of Chemistry, ‡Department of Geology and Geophysics and §the…

Shechtman’s quasicrystals win this year’s nobel prize

Title: Metallic Phase with Long-Range Orientational Order and No Translational Symmetry Authors: D. Shechtman, I. Blech1, D. Gratias2, and J. W. Cahn3 Journal: Physical Review Letters Affiliations: 1Department of Materials Engineering, Israel Institute of Technology Technion, 3200 Haifa, Israel. 2Centre d’Etudes de Chimie Metallurgique, Centre National de la Recherche Scientiftque,…

Applying to Grad School

Where should I apply?  What are my chances of getting accepted?  When are the applications due?  How much do they cost?  What application should I work on first?  Who should I get to write my letters of recommendation?  Is grad school even right for me?  I…

Light-Harvesting Metal-Organic Frameworks (MOFs): Efficient Strut-to-Strut Energy Transfer in Bodipy and Porphyrin-Based MOFs

Title: Light-Harvesting Metal-Organic Frameworks (MOFs): Efficient Strut-to-Strut Energy Transfer in Bodipy and Porphyrin-Based MOFs Authors: Chang Yeon Lee, Omar K. Farha, Bong Jin Hong, Amy A. Sarjeant, SonBinh T. Nguyen, and Joseph T. Hupp Journal: Journal of the American Chemical Society Affiliation: Department of Chemistry, Northwestern University, 2145…

My Favorite Reaction – Azide Alkyne Huisgen Cycloaddition

The azide alkyne Huisgen cycloaddition easily qualifies as my favorite reaction and my submission to the Chemistry Carnival.  It combines simplicity with efficiency in a way that is unmatched by most other chemistries.  From clicking side chains onto polymers to conveniently synthesizing a variety of natural…

Hybrid Photocatalyst for Hydrogen Production

Title: Nature-Driven Photochemistry for Catalytic Solar Hydrogen Production: A Photosystem I–Transition Metal Catalyst Hybrid  Authors: Lisa M. Utschig, Sunshine C. Silver, Karen L. Mulfort, and David M. Tiede Journal: Journal of the American Chemical Society Affiliation: * Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, Illinois…

Toward Functional Ni-SOD Biomimetics: Achieving a Structural/Electronic Correlation with Redox Dynamics

Title: Toward Functional Ni-SOD Biomimetics: Achieving a Structural/Electronic Correlation with Redox Dynamics Authors: Eric M. Gale†, Andrew C. Simmonett†, Joshua Telser‡, Henry F. Schaefer, III†, and Todd C. Harrop*† Journal: Inorganic Chemistry Affiliation: Department of Chemistry and Center for Computational Chemistry, The University of Georgia Department of Biological, Chemical and…

Surface science and electrical properties from a nice, short “reporter” molecule on the surface of a nanocrystal

Title: Thiocyanate-Capped Nanocrystal Colloids: Vibrational Reporter of Surface Chemistry and Solution-Based Route to Enhanced Coupling in Nanocrystal Solids Authors:  Aaron T. Fafarman, Weon-kyu Koh, Benjamin T. Diroll, David K. Kim, Dong-Kyun Ko, Soong Ju Oh, Xingchen Ye, Vicky Doan-Nguyen, Michael R. Crump, Danielle C. Reifsnyder, Christopher B. Murray, and Cherie R.…

A Protein-Based Approach for DNA Damage Sensing

Title: Turn-On DNA Damage Sensors for the Direct Detection of 8-Oxoguanine and Photoproducts in Native DNA             Authors: Jennifer L. Furman, Pui-Wing Mok, Ahmed H. Badran, and Indraneel Ghosh* Journal: Journal of the American Chemical Society Affiliation: Department of Chemistry and…

What chirality can do for your hydrogel

Title: Enhanced Mechanical Rigidity of Hydrogels Formed from Enantiomeric Peptide Assemblies Authors: Katelyn J. Nagy†‡, Michael C. Giano†‡, Albert Jin§, Darrin J. Pochanǁ, and Joel P. Schneider† Journal: Journal of the American Chemical Society Affiliation: †National Cancer Institute, Center for Cancer Research; ‡University of Delaware, Department…

A New Way to Make Polymers Click

Title: Additive-Free Clicking for Polymer Functionalization and Coupling by Tetrazine–Norbornene Chemistry Authors: Claire F. Hansell†, Pieter Espeel‡, Milan M. Stamenovi‡, Ian A. Barker†, Andrew P. Dove†, Filip E. Du Prez‡, and Rachel K. O’Reilly† Journal: Journal of the American Chemical Society Affiliation: †Department of Chemistry, University of…

New Hydrogels from Peptide Sequences Found in Nature

Title: Supramolecular hydrogels based on the epitope of potassium ion channels Authors: Yi Kuang, Yuan Gao, Junfeng Shi, Hsin-Chieh Lin and Bing Xu Journal: Chemical Communications Affiliation: Department of Chemistry, Brandeis University Supramolecular hydrogels are a growing field of research due to their biocompatibility and the…