Author: liminy0

A Simple Organometallic Fluoride Sensor

Title:  Stibonium Ions for the Fluorescence Turn-On Sensing of F– in Drinking Water at Parts per Million Concentrations DOI: 10.1021/ja308194w Author:  Iou-Sheng Ke a, Mykhaylo Myahkostupov b, Felix N. Castellano *b, and François P. Gabbaï *a Journal:  Journal of American Chemical Society Affiliation:  a) Department of Chemistry, Texas A&M University, College…

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Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond

Title:  Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond DOI:  10.1126/science.1221138 Author:  Holger Braunschweig, Rian D. Dewhurst, Kai Hammond, Jan Mies, Krzysztof Radacki, Alfredo Vargas Journal:  Science Affiliation:  Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany Take-home Importance According to the Authors:  Homoatomic triple…

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Electrocatalytically Active Graphene–Porphyrin MOF Composite for Oxygen Reduction Reaction

Title:  Electrocatalytically Active Graphene–Porphyrin MOF Composite for Oxygen Reduction Reaction DOI:  10.1021/ja211433h Author:  Maryam Jahan, Qiaoliang Bao, and Kian Ping Loh Journal:  Journal of the American Chemical Society Affiliation:  Graphene Research Centre, Department of Chemistry, National University of Singapore, Singapore Take-home Importance According to the Authors: By reacting the pyridine-functionalized graphene with…

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CO2 Reduction on Tin Electrodes and Enhanced Activity for Tin/Tin Oxide Thin-Film Catalysts

Title:  Tin Oxide Dependence of the CO2 Reduction Efficiency on Tin Electrodes and Enhanced Catalytic Activity for Tin/Tin-Oxide Thin Film Catalyst DOI:  10.1021/ja2108799 Author:  Yihong Chen and Matthew W. Kanan Journal:  Journal of the American Chemical Society Affiliation:  Department of Chemistry, Stanford University, Stanford, California, United…

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Copper (I) Hydroxide–Cuprice

Chemists probably would not willingly search for CuOH unless there is some theoretical basis for its existence. Without changing the oxidation states, a readied reaction could be 2 CuOH –> Cu2O + H2O. Its existence has been speculated on, now the really interesting work begins with the compound’s isolation (for a synthetic chemist).

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Synthesis and Characterization of the Phosphorus Triazides OP(N3)3 and SP(N3)3

Title: Synthesis and Characterization of the Phosphorus Triazides OP(N3)3 and SP(N3)3 Authors:  Xiaoqing Zeng, Eduard Bernhardt, Helmut Beckers, and Helge Willner Journal:  Inorganic Chemistry Affiliation:  FB C − Anorganische Chemie, Bergische Universität, Wuppertal, Germany Take-Home Importance according to the Authors:  Two explosive triazides of phosphorus(V), OP(N3)3…

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Continuous in situ generation and reaction of phosgene in a microflow system

Title:  Continuous in situ generation and reaction of phosgene in a microflow system Authors:  Shinichiro Fuse, Nobutake Tanabe, and Takashi Takahashi* Journal:  Chemical Communications Affiliation:  Department of Applied Chemistry, Tokyo Institute of Technology, Tokyo, Japan. Take-Home Importance according to the Authors:  Continuous in situ generation of…

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Electrochemical Mechanism of Ion–Ionophore Recognition at Plasticized Polymer Membrane/Water Interfaces

Title:  Electrochemical Mechanism of Ion–Ionophore Recognition at Plasticized Polymer Membrane/Water Interfaces Author:  Ryoichi Ishimatsu, Anahita Izadyar, Benjamin Kabagambe, Yushin Kim, Jiyeon Kim, and Shigeru Amemiya Journal:  Journal of the American Chemical Society Affiliation:  Department of Chemistry, University of Pittsburgh, 219 Parkman Avenue, Pittsburgh, Pennsylvania, 15260 Take…

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