Category: Catalysis

Bicarbonate Controlling the Rate of CO2 Reduction

This work shows that bicarbonate (HCO3-) is neither a general acid nor a reaction partner in the rate-limiting step of electrochemical CO2 reduction catalysis mediated by planar polycrystalline Au surfaces. Kinetic modeling studies and electrochemical experiments suggest that it acts as a proton donor in steps past the rate-limiting one and a buffer in the solution.

A New Dichlorination of Alkenes: A Radical Twist to a Long-sought Transformation

Title: Electrocatalytic Radical Dichlorination of Alkenes with Nucleophilic Chlorine Sources Authors: Niankai Fu, Gregory S. Sauer, and Song Lin Journal: Journal of the American Chemical Society http://pubs.acs.org/doi/10.1021/jacs.7b09388 Year: 2017 The unsaturated bond of an alkene is one of the most exploited functionalities inside the organic chemist’s…