Category: Catalysis

Go Ask Mother Nature—she’s got an answer

An overwhelming majority of scientists are in agreement—and that never happens—something must change before we reach the so-called “point-of-no-return”. The onset of the industrial era (and the associated benefits) encouraged a system that pollutes our environment in search of the largest possible profits. More recently, our voices have gotten louder, and large groups of society have dedicated themselves to uncovering the solutions to these problems. Perhaps, in this regard, Mother Nature still has lessons to offer.

Controlling Crystallinity and Porosity of Covalent Organic Frameworks with Hydrogen Bonding

This work reports a solvent-free solid-to-solid synthesis method for covalent organic frameworks (COFs), which is very promising from a greener and cleaner chemistry standpoint. The researchers found that hydrogen bonding within the starting material plays a key role on the porosity and crystallinity of the final COF.

Structure-Function Relationship in a Highly Efficient CO2 Reducing MOF

A structure-function relationship has been established for a cobalt containing Metal Organic Framework (MOF) that catalyzes carbon dioxide reduction very efficiently. It has been established that the hydroxyl groups coordinated to the metal co-operates to enhance the catalysis by forming H-bond network with CO2. Let’s learn how the authors performed a systematic and thorough investigation on these MOFs.