Category: Photochemistry

Shining Light on Aldehyde Synthesis

Photoredox catalysis is at it again! This time it is used to synthesize polysubstituted aldehydes – highly useful building blocks – from readily available styrenes and vinyl ethers.

How to Prevent Cannibalism in Catalysts

This work describes an approach to prevent self assimilation of catalysts to increase their lifetime. It also finds a Hammett correlation between different substituents present on the catalysts and the rate of catalysis in both homogeneous and heterogeneous phase.

Structure-Function Relationship in a Highly Efficient CO2 Reducing MOF

A structure-function relationship has been established for a cobalt containing Metal Organic Framework (MOF) that catalyzes carbon dioxide reduction very efficiently. It has been established that the hydroxyl groups coordinated to the metal co-operates to enhance the catalysis by forming H-bond network with CO2. Let’s learn how the authors performed a systematic and thorough investigation on these MOFs.

Designing and Understanding New Semiconductor Crystals

Solar panels are expensive because of the high-purity silicon present in them. A new material called perovskite rivals the solar conversion efficiency of silicon, but at a fraction of the cost. There is however still a lot of fundamental understanding to be done on perovskites, which these researchers do by studying analogous structures.

Carbon Monoxide: Future Therapeutic?

Carbon monoxide is probably one of the last things you would expect to see touted as a new therapeutic. How could this compound be used in medicine?